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Synthesis of new biosynthetically important diarylheptanoids and their oxa- and fluoro-analogues by three different strategies

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Baranovsky,  A.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Schmitt,  B.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Fowler,  D. J.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Schneider,  B.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Citation

Baranovsky, A., Schmitt, B., Fowler, D. J., & Schneider, B. (2003). Synthesis of new biosynthetically important diarylheptanoids and their oxa- and fluoro-analogues by three different strategies. Synthetic Communications, 33(6), 1019-1045. doi:10.1081/SCC-120016367.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-B5CB-9
Abstract
Wittig, aldol and Wittig-Horner reactions have been used to synthesize new diarylheptanoids, which are putative intermediates in phenylphenalenone biosynthesis in plants. The Wittig-Horner approach was most suitable and gave significantly higher yields