Synthesis and protein binding of (4-carboxybutyl)carbamoyl- substituted taxoids

Blitzke, T.; Baranovsky, A.; Schneider, B.

doi:10.1002/1522-2675(20010711)84:7<1989::AID-HLCA1989>3.0.CO;2-M

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Synthesis and protein binding of (4-carboxybutyl)carbamoyl- substituted taxoids

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Baranovsky, A.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Schneider, B.
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Blitzke, T., Baranovsky, A., & Schneider, B. (2001). Synthesis and protein binding of (4-carboxybutyl)carbamoyl- substituted taxoids. Helvetica Chimica Acta, 84(7), 1989-1995. doi:10.1002/1522-2675(20010711)84:7<1989:AID-HLCA1989>3.0.CO;2-M.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-B54E-1

Abstract

(4-Carboxybutyl)carbamates 5 and 6, as well as 10, derived from 10-O-deacetylbaccatin III (1) and paclitaxel (2), respectively, were synthesized by reaction of unprotected I and 2 ' -O- (methoxyacetyl)paclitaxel (8), respectively. with trimethylsilyl 5-