Synthesis of hexadeuterated 23-dehydroxybrassinosteroids

Khripach, V. A.; Zhabinskii, V. N.; Antonchik, A. P.; Konstantinova, O. V.; Schneider, Bernd

doi:10.1016/S0039-128X(02)00071-5

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Synthesis of hexadeuterated 23-dehydroxybrassinosteroids

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Schneider, Bernd
Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society;

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Citation

Khripach, V. A., Zhabinskii, V. N., Antonchik, A. P., Konstantinova, O. V., & Schneider, B. (2002). Synthesis of hexadeuterated 23-dehydroxybrassinosteroids. Steroids, 67(13-14), 1101-1108. doi:10.1016/S0039-128X(02)00071-5.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-B50F-F

Abstract

Two hexadeuterated brassinosteroids (BS) ([26,27-H-2(6)]-23- dehydroxycastasterone and [26,27-H-2(6)]-cathasterone) containing a hydroxy group at C-22 instead of the 22R,23R-diol function characteristic for most compounds of this class were prepared for