Absolute configuration and synthesis of (+)‐caudoxirene, the gamete‐releasing 
and gamete‐attracting pheromone of the brown alga Perithalia caudata 
(Phaeophyceae)

Wirth, D.; Boland, W.; Müller, D. G.

doi:10.1002/hlca.19920750311

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Absolute configuration and synthesis of (+)‐caudoxirene, the gamete‐releasing and gamete‐attracting pheromone of the brown alga Perithalia caudata (Phaeophyceae)

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Citation

Wirth, D., Boland, W., & Müller, D. G. (1992). Absolute configuration and synthesis of (+)‐caudoxirene, the gamete‐releasing and gamete‐attracting pheromone of the brown alga Perithalia caudata (Phaeophyceae). Helvetica Chimica Acta, 75(3), 751-758. doi:10.1002/hlca.19920750311.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A472-1

Abstract

The absolute configuration of the gamete-releasing and -attracting pheromone 2-vinyl-3-(5'-vinylcyclopent-2'-enyl)oxirane (= (+)-caudoxirene; (+)-1) of the marine brown alga Perithalia caudata is established as (2R,3R,1'S,5'S). Highly diastereoselective