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Synthesis of volicitin: a novel three-component Wittig approach to chiral 17-hydroxylinolenic acid

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Pohnert,  Georg
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Koch,  Thomas
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Boland,  Wilhelm
Department of Bioorganic Chemistry, Prof. Dr. W. Boland, MPI for Chemical Ecology, Max Planck Society;

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Citation

Pohnert, G., Koch, T., & Boland, W. (1999). Synthesis of volicitin: a novel three-component Wittig approach to chiral 17-hydroxylinolenic acid. Chemical Communications, (12), 1087-1088. doi:10.1039/A902020I.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A2DC-5
Abstract
A short stereoselective synthesis of both enantiomers of N-(17-hydroxylinolenoyl)-L-glutamine (volicitin) 12, an elicitor of plant volatile biosynthesis from beet armyworm salivary secretion, is described; the protected 17-hydroxylinolenic acid 4 moiety