Gas-chromatographic determination of the enantiomeric composition of epoxy 
alcohols

Konig, W. A.; Lutz, S.; Wenz, G.; Gorgen, G.; Neumann, C.; Gabler, A.; Boland, W.

doi:10.1002/anie.198901781

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Gas-chromatographic determination of the enantiomeric composition of epoxy alcohols

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Citation

Konig, W. A., Lutz, S., Wenz, G., Gorgen, G., Neumann, C., Gabler, A., et al. (1989). Gas-chromatographic determination of the enantiomeric composition of epoxy alcohols. Angewandte Chemie, International Edition in English, 28(2), 178-179. doi:10.1002/anie.198901781.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A131-D

Abstract

Enantiomeric excesses greater than 98% can now be determined exactly in the synthesis of chiral epoxy alcohols. Capillary chromatography on peralkylated cyclodextrins allows the trifluoroacetyl derivatives of epoxy alcohols such as (E)‐2,3‐epoxy‐4‐octynol (picture on the right) and 2,3‐epoxypropanol to be separated into their enantiomers within a few minutes.