Highly efficient synthesis of (+/-)-lamoxirene, the gamete- releasing and 
gamete-attracting pheromone of the Laminariales (Phaeophyta)

Hertweck, C.; Boland, Wilhelm

doi:10.1016/S0040-4020(97)01008-9

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Highly efficient synthesis of (+/-)-lamoxirene, the gamete- releasing and gamete-attracting pheromone of the Laminariales (Phaeophyta)

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Hertweck, C.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Boland, Wilhelm
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Hertweck, C., & Boland, W. (1997). Highly efficient synthesis of (+/-)-lamoxirene, the gamete- releasing and gamete-attracting pheromone of the Laminariales (Phaeophyta). Tetrahedron, 53(43), 14651-14654. doi:10.1016/S0040-4020(97)01008-9.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A0A7-D

Abstract

An efficient and highly diastereoselective synthesis of lamoxirene (cis-2-cyclohepta-2,5-dienyl-3-vinyloxirane, 4), the gamete releasing and -attracting pheromone of the Laminariales (Phaeophyceae), is reported. Ethyl cyclohepta-2,5-diene carboxylate (7