Efficient and flexible synthesis of chiral gamma- and delta-lactones

Habel, A.; Boland, W.

doi:10.1039/b801514g

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Efficient and flexible synthesis of chiral gamma- and delta-lactones

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Habel, A.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Boland, W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Habel, A., & Boland, W. (2008). Efficient and flexible synthesis of chiral gamma- and delta-lactones. Organic & Biomolecular Chemistry, 6(9), 1601-1604. doi:10.1039/b801514g.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A03F-8

Abstract

An efficient and highly flexible synthesis for chiral gamma- and delta-lactones with high enantiomeric purity is described (> 99% ee and 57-87% overall yield). The protocol involves alkylation of chiral 1,2-oxiranes with terminally unsaturated Grignard