C–H carbonylation: In situ acyl triflates ace it

Lee, Yong Ho; Morandi, Bill

doi:10.1038/nchem.2934

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C–H carbonylation: In situ acyl triflates ace it

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Lee, Yong Ho
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Morandi, Bill
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Lee, Y. H., & Morandi, B. (2018). C–H carbonylation: In situ acyl triflates ace it. Nature Chemistry, 10(2), 116-117. doi:10.1038/nchem.2934.

Cite as: https://hdl.handle.net/21.11116/0000-0001-6C1F-5

Abstract

A simple palladium catalyst has mediated the facile formation of aroyl triflates — an extremely reactive class of electrophiles. These intermediates, generated in situ, enable the Friedel–Crafts acylation of traditionally unreactive arenes, addressing a significant gap in C–H carbonylation methodology.