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Selective production of glycols from xylitol over Ru on covalent triazine frameworks - suppressing decarbonylation reactions

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Weidenthaler,  Claudia
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Beine, A. K., Krüger, A. J. D., Artz, J., Weidenthaler, C., Glotzbach, C., Hausoul, P. J. C., et al. (2018). Selective production of glycols from xylitol over Ru on covalent triazine frameworks - suppressing decarbonylation reactions. Green Chemistry, 20(6), 1316-1322. doi:10.1039/C8GC00208H.


Cite as: https://hdl.handle.net/21.11116/0000-0001-2BA5-5
Abstract
Ru on covaltent triazine frameworks (CTF) are highly active and selective catalysts for the conversion of xylitol to glycols (80% C-yield) in basic media. With increasing N-content decarbonylation reactions are suppressed leading to high glycol selectivity. The suppression can be attributed to the presence of N in the support and to metal-support interactions. The catalysts exhibit high stability and could be recycled 5 times with minor loss of activity.