English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal Alkynes

MPS-Authors
/persons/resource/persons209393

Ye,  Fei
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Chen,  Junting
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons198096

Ritter,  Tobias
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Ye, F., Chen, J., & Ritter, T. (2017). Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal Alkynes. Journal of the American Chemical Society, 139(21), 7184-7187. doi:10.1021/jacs.7b03749.


Cite as: https://hdl.handle.net/21.11116/0000-0000-84C1-0
Abstract
We report the first highly stereo- and regioselective hydrocyanation of terminal alkynes to furnish E-configured alkenyl nitriles. Acrylonitriles can be accessed on gram scale with broad substrate scope and functional group tolerance. The hydrocyanation reaction employs acetone cyanohydrin as a practical alternative to HCN gas.