Successive Phase Transitions in Fe2+ Ladder Compounds Sr2Fe3Ch2O3 (Ch = S, Se)

Lai, Kwing To; Adler, Peter; Prots, Yurii; Hu, Zhiwei; Kuo, Chang-Yang; Pi, Tun-Wen; Valldor, Martin

doi:10.1021/acs.inorgchem.7b02042

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Successive Phase Transitions in Fe²⁺ Ladder Compounds Sr₂Fe₃Ch₂O₃ (Ch = S, Se)

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Lai, Kwing To
Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126506

Adler, Peter
Peter Adler, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126806

Prots, Yurii
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126666

Hu, Zhiwei
Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kuo, Chang-Yang
Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126889

Valldor, Martin
Martin Valldor, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Lai, K. T., Adler, P., Prots, Y., Hu, Z., Kuo, C.-Y., Pi, T.-W., et al. (2017). Successive Phase Transitions in Fe²⁺ Ladder Compounds Sr₂Fe₃Ch₂O₃ (Ch = S, Se). Inorganic Chemistry, 56(20), 12606-12614. doi:10.1021/acs.inorgchem.7b02042.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002E-2544-5

Abstract

Small single crystals of Sr2Fe3Ch2O3 (Ch = S, Se) have been synthesized by flux methods, and bulk materials have been obtained by solid state reactions. Both compounds are isostructural to the compound Sr2Co3S2O3 (space group Pbam), which contains a novel hybrid spin ladder: a combination of a 2-leg rectangular ladder and a necklace ladder. The 2-leg ladder acts as a well-defined magnetic entity, while intimate magnetic coupling to the necklace ladder induces three successive phase transitions in the range of 40–120 K in each composition (Ch = S or Se), as revealed by Mössbauer spectroscopy, thermodynamics, and magnetometry. The complex magnetic behaviors can be explained by the unique spin–lattice topology.