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Journal Article

Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal Alkynes

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Yuting, Chen
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ye, Fei
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ritter, Tobias
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Yuting, C., Ye, F., & Ritter, T. (2017). Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal Alkynes. Journal of the American Chemical Society, 7184-7187. doi: 10.1021/jacs.7b03749.

Abstract

We report the first highly stereo- and regioselective hydrocyanation of terminal alkynes to furnish E-configured alkenyl nitriles. Acrylonitriles can be accessed on gram scale with broad substrate scope and functional group tolerance. The hydrocyanation reaction employs acetone cyanohydrin as a practical alternative to HCN gas.