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Journal Article

Dissolution behaviour and activation of selenium in phosphonium based ionic liquids

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Ruck,  Michael
Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Zhang, T., Schwedtmann, K., Weigand, J. J., Doert, T., & Ruck, M. (2017). Dissolution behaviour and activation of selenium in phosphonium based ionic liquids. Chemical Communications, 53(54), 7588-7591. doi:10.1039/c7cc03564k.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-AEFF-0
Abstract
The dissolution behaviour of grey selenium in phosphonium based ionic liquids (ILs) has been investigated for the first time by P-31 and Se-77 nuclear magnetic resonance (NMR) experiments. The investigations evidence the formation of trialkylphosphane selenides which can serve as a selenium reservoir in the subsequent formation of metal selenides.