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Journal Article

Dynamically and quasiforbidden transitions in photoionization of open-shell atoms: A combined experimental and theoretical study.

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Canton,  S. E.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Cubaynes, D., Meyer, M., Grum-Grzhimailo, A. N., Bizau, J. M., Kennedy, E. T., Bozek, J., et al. (in preparation). Dynamically and quasiforbidden transitions in photoionization of open-shell atoms: A combined experimental and theoretical study.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-8852-6
Abstract
Completely fine-structure-resolved photoelectron spectra produced from sodium atoms selectively excited into the Na∗ 2p63p 2P1/2 and 2P3/2 states were obtained using a third generation synchrotron source in conjunction with laser pumping and high-resolution spectrometry. The spectra show dramatically different behaviors. The strong variations observed in the regions of the Na+ 2p53p1,3LJ photolines and the Na+ 2p54p 1,3LJ shakeup satellites are explained within a generalized geometrical model, ac