Probing the molecular environment using spin-resolved photoelectron 
spectroscopy.

Turri, G.; Snell , G.; Langer, B.; Martins, M.; Kukk, E.; Canton, S. E.; Bilodeau, R. C.; Cherepkov, N.; Bozek, J. D.; Kilcoyne , A. L.; Berrah, N.

doi:10.1103/PhysRevLett.92.013001

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Probing the molecular environment using spin-resolved photoelectron spectroscopy.

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Canton, S. E.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Turri, G., Snell, G., Langer, B., Martins, M., Kukk, E., Canton, S. E., et al. (2004). Probing the molecular environment using spin-resolved photoelectron spectroscopy. Physical Review Letters, 92(1): 013001. doi:10.1103/PhysRevLett.92.013001.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-882A-2

Abstract

Angle- and spin-resolved photoelectron spectroscopy with linearly and circularly polarized synchrotron radiation were used to study the electronic structure of model triatomic molecules, hydrogen sulfide, and carbonyl sulfide. The spin-polarization measurements of the molecular field split components of the S 2p photolines revealed a strong effect of the different molecular environments. The validity of simple atomic models to explain the results is discussed.