Datensatz

Zusammenfassung

We present a top-down approach to infer and quantify rain-induced emission pulses of NOx ( NO + NO2), stemming from biotic emissions of NO from soils, from satellite-borne measurements of NO2. This is achieved by synchronizing time series at single grid pixels according to the first day of rain after a dry spell of prescribed duration. The full track of the temporal evolution several weeks before and after a rain pulse is retained with daily resolution. These are needed for a sophisticated background correction, which accounts for seasonal variations in the time series and allows for improved quantification of rain-induced soil emissions. The method is applied globally and provides constraints on pulsed soil emissions of NOx in regions where the NOx budget is seasonally dominated by soil emissions. We find strong peaks of enhanced NO2 vertical column densities (VCDs) induced by the first intense precipitation after prolonged droughts in many semi-arid regions of the world, in particular in the Sahel. Detailed investigations show that the rain-induced NO2 pulse detected by the OMI (Ozone Monitoring Instrument), GOME-2 and SCIAMACHY satellite instruments could not be explained by other sources, such as biomass burning or lightning, or by retrieval artefacts (e.g. due to clouds). For the Sahel region, absolute enhancements of the NO2 VCDs on the first day of rain based on OMI measurements 2007-2010 are on average 4 x 10(14) molec cm(-2) and exceed 1 x 10(15) molec cm(-2) for individual grid cells. Assuming a NOx lifetime of 4 h, this corresponds to soil NOx emissions in the range of 6 up to 65 ng N m(-2) s(-1), which is in good agreement with literature values. Apart from the clear first-day peak, NO2 VCDs are moderately enhanced (2 x 10(14) molec cm(-2)) compared to the background over the following 2 weeks, suggesting potential further emissions during that period of about 3.3 ng N m(-2) s(-1). The pulsed emissions contribute about 21-44% to total soil NOx emissions over the Sahel.