Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
Zur Ablage hinzufügen
  Lokale TagsFreigabegeschichteDetailsÜbersicht

Freigegeben
Zeitschriftenartikel

The electrochemical reduction of a cadmium cryptate on a mercury electrode in acetonitrile.

MPG-Autoren
/persons/resource/persons15886

Stroka,  J.
Research Group Electrochemistry and Reaction Kinetics in Solution, MPI for biophysical chemistry, Max Planck Society;

/persons/resource/persons15781

Schneider,  H.
Research Group Electrochemistry and Reaction Kinetics in Solution, MPI for biophysical chemistry, Max Planck Society;

Externe Ressourcen
Es sind keine externen Ressourcen hinterlegt
Volltexte (beschränkter Zugriff)
Für Ihren IP-Bereich sind aktuell keine Volltexte freigegeben.
Volltexte (frei zugänglich)

2382631.pdf
(Verlagsversion), 749KB

Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Stroka, J., Cox, B. G., & Schneider, H. (1989). The electrochemical reduction of a cadmium cryptate on a mercury electrode in acetonitrile. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 266(2), 337-348. doi:10.1016/0022-0728(89)85079-X.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-002C-3E40-3
Zusammenfassung
The reduction of the Cd(2,2,2)2+ complex has been studied in acetonitrile using polarography, chronocoulometry, and cyclic voltammetry. The corresponding kinetic parameters have been calculated and are compared with those obtained for the solvated cadmium cation in the same solvent. The study of the electrochemical reduction mechanism showed that the final stable products are the free ligand (2,2,2) and cadmium-amalgam. The stability constant of the cadmium cryptate in acetonitrile has been estimated as log Ks = 17.3 from the electrochemical measurements.