Catalytic Asymmetric Reductive Condensation of N–H Imines: Synthesis of C2
-Symmetric Secondary Amines

Wakchaure, Vijay; List, Benjamin

doi:10.1002/anie.201608329

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Catalytic Asymmetric Reductive Condensation of N–H Imines: Synthesis of C₂-Symmetric Secondary Amines

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Wakchaure, Vijay
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Wakchaure, V., & List, B. (2016). Catalytic Asymmetric Reductive Condensation of N–H Imines: Synthesis of C₂-Symmetric Secondary Amines. Angewandte Chemie International Edition in English, 55(51), 15775-15778. doi:10.1002/anie.201608329.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-2417-0

Abstract

A highly diastereoselective and enantioselective Brønsted acid catalyzed reductive condensation of N−H imines was developed. This reaction is catalyzed by a chiral disulfonimide (DSI), uses Hantzsch esters as a hydrogen source, and delivers useful C₂-symmetric secondary amines.