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A Cu(ii) metal-organic framework as a recyclable catalyst for ARGET ATRP

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Lee,  Hui-Chun
Bernhard Schmidt, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Schmidt,  Bernhard V. K. J.
Bernhard Schmidt, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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2367228.pdf
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2367228_supp.pdf
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Citation

Lee, H.-C., Antonietti, M., & Schmidt, B. V. K. J. (2016). A Cu(ii) metal-organic framework as a recyclable catalyst for ARGET ATRP. Polymer Chemistry, 7(47), 7199-7203. doi:10.1039/C6PY01844K.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-0F8A-2
Abstract
A Cu(ii) MOF can serve as an efficient catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), e.g. for the synthesis of poly(benzyl methacrylate) (PBzMA) and polystyrene (PS). Furthermore, poly(isoprene) (PI) and poly(4-vinylpyridine) (P4VP) can be formed in a controlled fashion as well, which used to be challenging to achieve by traditional strategies. Taking advantage of the heterogeneous nature of the catalyst, recycling via centrifugation and repeated utilization for at least six cycles are demonstrated.