Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids

Groh, Matthias F.; Wolff, Alexander; Grasser, Matthias A.; Ruck, Michael

doi:10.3390/ijms17091452

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Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids

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Ruck, Michael
Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Groh, M. F., Wolff, A., Grasser, M. A., & Ruck, M. (2016). Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids. International Journal of Molecular Sciences, 17(9): 1452, pp. 1-18. doi:10.3390/ijms17091452.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-BC6B-1

Abstract

Ionic liquids (ILs) have been proven to be valuable reaction media for the synthesis of inorganic materials among an abundance of other applications in different fields of chemistry. Up to now, the syntheses have remained mostly black boxes; and researchers have to resort to trial-and-error in order to establish a new synthetic route to a specific compound. This review comprises decisive reaction parameters and techniques for the directed synthesis of polyions of heavy main-group elements (fourth period and beyond) in ILs. Several families of compounds are presented ranging from polyhalides over carbonyl complexes and selenidostannates to homo and heteropolycations.