Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins

von Klitzing, Regine; Stehl, Dimitrij; Pogrzeba, Tobias; Schomäcker, Reinhard; Minullina, Renata; Panchal, Abhishek; Konnova, Svetlana; Fakhrullin, Rawil; Koetz, Joachim; Möhwald, Helmuth; Lvov, Yuri

doi:10.1002/admi.201600435

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Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins

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Möhwald, Helmuth
Grenzflächen, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

von Klitzing, R., Stehl, D., Pogrzeba, T., Schomäcker, R., Minullina, R., Panchal, A., et al. (2017). Halloysites Stabilized Emulsions for Hydroformylation of Long Chain Olefins. Advanced Materials Interfaces, 4(1): 1600435. doi:10.1002/admi.201600435.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-528D-8

Abstract

Halloysites as tubular alumosilicates are introduced as inexpensive natural nanoparticles to form and stabilize oil–water emulsions. This stabilized emulsion is shown to enable efficient interfacial catalytic reactions. Yield, selectivity, and product separation can be tremendously enhanced, e.g., for the hydroformylation reaction of dodecene to tridecanal. In perspective, this type of formulation may be used for oil spill dispersions. The key elements of the described formulations are clay nanotubes (halloysites) which are highly anisometric, can be filled by helper molecules, and are abundantly available in thousands of tons, making this technology scalable for industrial applications.