English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Lipopolysaccharide core region of Hafnia alvei: structure elucidation using chemical methods, gas chromatography-mass spectrometry, and NMR spectroscopy

MPS-Authors
/persons/resource/persons123154

Dabrowski,  Ursula
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons92575

Dabrowski,  Janusz
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://www.sciencedirect.com/science/article/pii/000862159400266I/pdf?md5=c69b3b6d48aead635aa2c71809b01f06&pid=1-s2.0-000862159400266I-main.pdf
(Any fulltext)

http://dx.doi.org/10.1016/0008-6215(94)00266-I
(Any fulltext)

Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Gamian, A., Katzenellenbogen, E., Romanowska, E., Dabrowski, U., & Dabrowski, J. (1995). Lipopolysaccharide core region of Hafnia alvei: structure elucidation using chemical methods, gas chromatography-mass spectrometry, and NMR spectroscopy. Carbohydrate Research, 266(2), 221-228. doi:10.1016/0008-6215(94)00266-I.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-420A-F
Abstract
Sugar and methylation analysis with the use of gas chromatography+mass spectrometry and lit NMR spectroscopy proved that the core oligosaccharides isolated from lipopolysaccharides of eight Hajhia alvei strains have the identical hexasaccharide skeleton. However, tH,3tP heterocorrelatcd spectra showed that the phosphorylation pattern is not the same. The branched heptose for the ATCC 13337, 1187, 2, 1191, 1196, 1220, and 481L strains is pbosphorylated as in the following formula, where P =-O-P(O) (O-)2 and P-PEtN=[-O-P(O) (O-)]2-O(CH2) 2NH+3 α-LD-Hepp 1 ↓ 7 α-D-Glcp-(1 → 3) -α-D-Glcp-(1 →3)-α-LD-Hepp-(1 → 3)- α-LD-Hepp- ( 1 → 5 )-Kdo |4|4 P P-P-EtN