Condensed-Phase, Halogen-Bonded CF3I and C2F5I Adducts for Perfluoroalkylation 
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Sladojevich, Fillippo; McNeill, Eric; Zheng, Shao-Liang; Ritter, Tobias; Börgel, Jonas

doi:DOI: 10.1002/anie.201410954

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Condensed-Phase, Halogen-Bonded CF₃I and C₂F₅I Adducts for Perfluoroalkylation Reactions

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Ritter, Tobias
Harvard Univ, Dept Chem & Chem Biol;
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Börgel, Jonas
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Sladojevich, F., McNeill, E., Zheng, S.-L., Ritter, T., & Börgel, J. (2015). Condensed-Phase, Halogen-Bonded CF₃I and C₂F₅I Adducts for Perfluoroalkylation Reactions. Angewandte Chemie International Edition in English, (12), 3712-3716. doi:DOI: 10.1002/anie.201410954.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-784C-A

Abstract

A family of practical, liquid trifluoromethylation and pentafluoroethylation reagents is described. We show how halogen bonding can be used to obtain easily handled liquid reagents from gaseous CF₃I and CF₃CF₂I. The synthetic utility of the new reagents is exemplified by a novel direct arene trifluoromethylation reaction as well as adaptations of other perfluoroalkylation reactions.