Alkyl Aryl Ether Bond Formation with PhenoFluor

Shen, Xiao; Neumann, Constanze. N; Kleinlein, Claudia; Goldberg, Nathaniel W.; Ritter, Tobias

doi:10.1002/anie.201500902

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Alkyl Aryl Ether Bond Formation with PhenoFluor

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Ritter, Tobias
Department of Chemistry and Chemical Biology, Harvard University;
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Shen, X., Neumann, C. N., Kleinlein, C., Goldberg, N. W., & Ritter, T. (2015). Alkyl Aryl Ether Bond Formation with PhenoFluor. Angewandte Chemie International Edition in English, 54(19), 5662-5665. doi:10.1002/anie.201500902.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002B-84B8-C

Abstract

An alkyl aryl ether bond formation reaction between phenols and primary and secondary alcohols with PhenoFluor has been developed. The reaction features a broad substrate scope and tolerates many functional groups, and substrates that are challenging for more conventional ether bond forming processes may be coupled. A preliminary mechanistic study indicates reactivity distinct from conventional ether bond formation.