Surface Adsorption of sulfonated poly(phenylene sulfone)/C14TAB Mixtures and 
its Correlation with Foam Film Stability

Uhlig, Martin; Miller, Reinhard; Klitzing, Regine V

doi:10.1039/C6CP02256A

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Surface Adsorption of sulfonated poly(phenylene sulfone)/C₁₄TAB Mixtures and its Correlation with Foam Film Stability

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Miller, Reinhard
Reinhard Miller, Biomaterialien, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Uhlig, M., Miller, R., & Klitzing, R. V. (2016). Surface Adsorption of sulfonated poly(phenylene sulfone)/C₁₄TAB Mixtures and its Correlation with Foam Film Stability. Physical Chemistry Chemical Physics, 18(27), 18414-18423. doi:10.1039/C6CP02256A.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002A-EAE6-9

Abstract

Polyelectrolyte/surfactant mixtures of rigid monosulfonated poly(phenylene sulfone) (sPSO2-220) and tetradecyl trimethylammonium bromide (C14TAB) were investigated by surface tension, surface elasticity and foam film stability measurements. The results were compared to former measurements of polyelectrolyte/surfactant mixtures containing more flexible polyelectrolytes (PAMPS or PSS and C14TAB). For all polyelectrolyte/surfactant mixtures an increased surface adsorption in comparison to the pure surfactant was detected. Moreover, sPSO2-220/C14TAB mixtures showed a much higher surface activity and foam film stability than mixtures with more flexible polyelectrolytes. The results presented give insight into the surface adsorption and foam film formation of rigid polyelectrolyte/surfactant mixtures. Therefore, this study helps to understand the role of polyelectrolyte backbone rigidity in the formation and stabilization of foam films made from polyelectrolyte/surfactant mixtures.