English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  DetailsSummary

Released
Journal Article

Molecular structure of di­ethylaminoalane in the solid state: an X-ray powder diffraction, DFT calculation and Raman spectroscopy study

MPS-Authors
/persons/resource/persons181104

Bernert,  Thomas
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons183469

Ley,  Morton Brix
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58541

Felderhoff,  Michael
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons59100

Weidenthaler,  Claudia
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Bernert, T., Ley, M. B., Ruiz-Fuertes, J., Fischer, M., Felderhoff, M., & Weidenthaler, C. (2016). Molecular structure of di­ethylaminoalane in the solid state: an X-ray powder diffraction, DFT calculation and Raman spectroscopy study. Acta Crystallographica Section B, 72, 232-240. doi:10.1107/S2052520616000093.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002A-2970-8
Abstract
The crystal structure of diethylaminoalane, [H2Al—N(C2H5)2]2, was determined by X-ray powder diffraction in conjunction with DFT calculations. Diethyl­aminoalane crystallizes in the monoclinic space group P21/c with a = 7.4020 (2), b = 12.9663 (3), c = 7.2878 (2) Å and β = 90.660 (2)° at 293 K. The crystal structure was confirmed by DFT calculations and Raman spectroscopy. The molecular structure of diethylaminoalane consists of dimers of [H2Al—N(CH2CH3)2] in which an Al2N2 four-membered ring is formed by a center of inversion. Such an arrangement of the aminoalane moieties in the crystal structure is well known for this class of compound, as shown by the comparison with ethylmethyl­aminoalane and diisopropylaminoalane.