Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

Fechler, Nina; Zussblatt, Niels P.; Rothe, Regina; Schlögl, Robert; Willinger, Marc Georg; Chmelka, Bradley F.; Antonietti, Markus

doi:10.1002/adma.201501503

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Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

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Fechler, Nina
Nina Fechler, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Rothe, Regina
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

/persons/resource/persons22071

Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22243

Willinger, Marc Georg
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
MPI for Chemical Energy Conversion;

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Antonietti, Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Preprint_Carbonnitride Materials Paper-1.pdf
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引用

Fechler, N., Zussblatt, N. P., Rothe, R., Schlögl, R., Willinger, M. G., Chmelka, B. F., & Antonietti, M. (2016). Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content. Advanced Materials, 28(6), 1287-1294. doi:10.1002/adma.201501503.

引用: https://hdl.handle.net/11858/00-001M-0000-0029-CF34-9

要旨

Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid-crystalline- like phases that can be processed. The architecture of phenol/ketone acts as structure-donating motif, while urea serves as melting-point reduction agent. Condensation at elevated temperatures results in nitrogen-containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.