Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Zeitschriftenartikel

On the relation between population kinetics and state-to-state rate coefficients for vibrational energy transfer.

MPG-Autoren
/persons/resource/persons14962

Dashevskaya,  E.I.
Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society;

/persons/resource/persons15454

Litvin,  I.
Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society;

/persons/resource/persons15586

Nikitin,  E. E.
Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society;

Volltexte (beschränkter Zugriff)
Für Ihren IP-Bereich sind aktuell keine Volltexte freigegeben.
Volltexte (frei zugänglich)

2230841.pdf
(Verlagsversion), 2MB

Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Dashevskaya, E., Litvin, I., & Nikitin, E. E. (2015). On the relation between population kinetics and state-to-state rate coefficients for vibrational energy transfer. Zeitschrift für Physikalische Chemie, 229(10-12), 1561-1574. doi:10.1515/zpch-2015-0597.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-0029-1D28-9
Zusammenfassung
The relation between time-dependent population of vibrational state and collision-induced state-to-state rate coefficients is discussed within the Landau–Teller kinetic equations for the relaxation of harmonic oscillators in a heat bath. In particular, the increase of the populations in the first and the second vibrational state of an initially cold oscillator shows a considerable variety of its relation to a single Landau–Teller state-to-state rate coefficient. It is suggested that this variety should be kept in mind when experimental studies of the relaxation of specific level are analyzed.