Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Zeitschriftenartikel

Hydrogen bonding in liquid water probed by resonant Auger-electron spectroscopy

MPG-Autoren
/persons/resource/persons15052

Faubel,  M.
Group Spectroscopy of aqueous surfaces, Department of Dynamics of Complex Fluids, Max Planck Institute for Dynamics and Self-Organization, Max Planck Society;

Externe Ressourcen
Es sind keine externen Ressourcen hinterlegt
Volltexte (beschränkter Zugriff)
Für Ihren IP-Bereich sind aktuell keine Volltexte freigegeben.
Volltexte (frei zugänglich)
Es sind keine frei zugänglichen Volltexte in PuRe verfügbar
Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Winter, B., Hergenhahn, U., Faubel, M., Björneholm, O., & Hertel, I. V. (2007). Hydrogen bonding in liquid water probed by resonant Auger-electron spectroscopy. Journal of Chemical Physics, 127(9): 094501. Retrieved from 10.1063/1.2770457.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-0029-13FD-E
Zusammenfassung
We have measured resonant and off-resonant Auger-electron spectra of liquid water. Continuumlike transitions near and above the O1s vertical ionization energy are identified by the characteristic normal Auger-electron spectra. On the contrary, well-resolved spectator shifts of the main Auger-electron peak are observed at the liquid-water O1s absorption main edge and near the absorption pre-edge. The shifts of 1.4 and 1.9 eV arise from the localized nature of the excitation. Excited-state localization/delocalization is also discussed for the analogous vacuum ultraviolet (VUV) transitions, and we point out the similarities between x-ray and VUV absorption spectra of liquid water.