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Journal Article

Renewable pyridinium ionic liquids from the continuous hydrothermal decarboxylation of furfural-amino acid derived pyridinium zwitterions

MPS-Authors
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Kirchhecker,  Sarah
Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Tröger-Müller,  Steffen
Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Esposito,  Davide
Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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2171305.pdf
(Publisher version), 872KB

Supplementary Material (public)

2171305_supp.pdf
(Supplementary material), 2MB

Citation

Kirchhecker, S., Tröger-Müller, S., Bake, S., Antonietti, M., Taubert, A., & Esposito, D. (2015). Renewable pyridinium ionic liquids from the continuous hydrothermal decarboxylation of furfural-amino acid derived pyridinium zwitterions. Green Chemistry, 17(8), 4151-4156. doi:10.1039/C5GC00913H.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0027-BD5C-2
Abstract
Fully renewable pyridinium ionic liquids were synthesised via the hydrothermal decarboxylation of pyridinium zwitterions derived from furfural and amino acids in flow. The functionality of the resulting ionic liquid (IL) can be tuned by choice of different amino acids as well as different natural carboxylic acids as the counterions. A representative member of this new class of ionic liquids was successfully used for the synthesis of ionogels and as a solvent for the Heck coupling.