Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed 
Oxide

Lunkenbein, Thomas; Girgsdies, Frank; Wernbacher, Anna Maria; Noack, Johannes; Auffermann, G.; Yasuhara, Akira; Klein-Hoffmann, Achim; Ueda, Wataru; Eichelbaum, Maik; Trunschke, Annette; Schlögl, Robert; Willinger, Marc Georg

doi:10.1002/anie.201502236

Item

ITEM ACTIONSEXPORT

Add to Basket

Please note that a newer version of this item is available:
https://pure.mpg.de/pubman/item/item_2163128_9

DetailsSummary

Released

Journal Article

Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide

MPS-Authors

/persons/resource/persons41515

Lunkenbein, Thomas
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21557

Girgsdies, Frank
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons39196

Wernbacher, Anna Maria
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons71845

Noack, Johannes
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons126525

Auffermann, G.
Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons21731

Klein-Hoffmann, Achim
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21485

Eichelbaum, Maik
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22181

Trunschke, Annette
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22071

Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
Max-Planck-Institut für Chemische Energiekonversion;

/persons/resource/persons22243

Willinger, Marc Georg
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

2163128.pdf
(Any fulltext), 605KB

Supplementary Material (public)

There is no public supplementary material available

Citation

Lunkenbein, T., Girgsdies, F., Wernbacher, A. M., Noack, J., Auffermann, G., Yasuhara, A., et al. (2015). Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide. Angewandte Chemie International Edition, 54(23), 6828-6831. doi:10.1002/anie.201502236.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0027-A36E-F

Abstract

Complex Mo,V-based mixed oxides that crystallize in the orthorhombic M1-type structure are promising candidates for the selective oxidation of small alkanes. The oxygen sublattice of such a complex oxide has been studied by annular bright field scanning transmission electron microscopy. The recorded micrographs directly display the local distortion in the metal oxygen octahedra. From the degree of distortion we are able to draw conclusions on the distribution of oxidation states in the cation columns at different sites. The results are supported by X-ray diffraction and electron paramagnetic resonance measurements that provide integral details about the crystal structure and spin coupling, respectively.