Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and 
Cyclohexanones

Morandi, Bill; Carreira, Erick M.

doi:10.1002/anie.201103526

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Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones

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Morandi, Bill
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Laboratorium für Organische Chemie, ETH Zürich, 8093 Zürich (Switzerland) ;

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Citation

Morandi, B., & Carreira, E. M. (2011). Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones. Angewandte Chemie International Edition, 50(39), 9085-9088. doi:10.1002/anie.201103526.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0026-A209-E

Abstract

A trifluoromethylated symphony! A new transformation involving trifluoromethyl diazomethane generated in situ has been developed that allows direct access to trifluoroethyl ketone derivatives from aldehyde and cyclohexanone compounds.