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Regioselective Wacker Oxidation of Internal Alkenes: Rapid Access to Functionalized Ketones Facilitated by Cross-Metathesis

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Morandi,  Bill
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA);
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Morandi, B., Wickens, Z. K., & Grubbs, R. H. (2013). Regioselective Wacker Oxidation of Internal Alkenes: Rapid Access to Functionalized Ketones Facilitated by Cross-Metathesis. Angewandte Chemie International Edition, 52(37), 9751-9754. doi:10.1002/anie.201303587.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0025-BA8A-7
Abstract
Wacka wacka: The title reaction makes use of a wide range of directing groups (DG) to enable the highly regioselective oxidation of alkenes, and occurs predictably at the distal position. Both E and Z alkenes afford valuable functionalized ketones and cross-metathesis was shown to facilitate the