English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Synthesis and Structure of the Formaldehyde Complex [(tmeda)Ni(C2H4)(H2CO)]

MPS-Authors

Schröder,  Wolfgang
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58898

Pörschke,  Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons59057

Tsay,  Y.-H.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58723

Krüger,  Carl
Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Schröder, W., Pörschke, K.-R., Tsay, Y.-H., & Krüger, C. (1987). Synthesis and Structure of the Formaldehyde Complex [(tmeda)Ni(C2H4)(H2CO)]. Angewandte Chemie International Edition, 26(9), 919-921. doi:10.1002/anie.198709191.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-B8F3-C
Abstract
The title complex 1 containing ethene and formaldehyde can be obtained in up to 35% yield in the form of orange-red crystals that are stable up to −15°C by reaction of tris(ethene)nickel, paraformaldehyde, and N,N,N′,N′-tetramethylethylenediamine (TMEDA). Unlike formaldehyde complexes of strongly oxophilic metals, in 1 the Ni-C bond is shorter than the Ni-O bond (1.936(2) and 1.966(1) Å, resp.). 1 is of interest as a model compound for intermediates of the Fischer-Tropsch synthesis.