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Journal Article

Mono- and Dinuclear Nickel(0) Complexes of Butadiyne

MPS-Authors

Bonrath,  Werner
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pörschke,  Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Wilke,  Günther
Research Department Wilke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Angermund,  Klaus
Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Krüger,  Carl
Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bonrath, W., Pörschke, K.-R., Wilke, G., Angermund, K., & Krüger, C. (1988). Mono- and Dinuclear Nickel(0) Complexes of Butadiyne. Angewandte Chemie International Edition, 27(6), 833-835. doi:10.1002/anie.198808331.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-BF52-B
Abstract
The nickel(0) complex 1 containing the extremely easily polymerizable and explosive ligand butadiyne is crystalline and stable at room temperature under inert gas. Complex 1 and the analogous mononuclear complex can be interconverted. Their synthesis opens up new approaches to the commercial use of butadiyne, which is a byproduct of acetylene production (n = 2,3).