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Journal Article

A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

MPS-Authors
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Wang,  Feng
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Richter,  Felix Herrmann
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Prieto,  Gonzalo
Research Group Prieto, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Weidenthaler,  Claudia
Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Bongard,  Hans-Josef
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth,  Ferdi
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

anie_201404912_sm_miscellaneous_information.pdf
(Supplementary material), 865KB

anie_201404912_sm_movie_s1.mov
(Supplementary material), 17MB

Citation

Wang, F., Mielby, J., Richter, F. H., Wang, G., Prieto, G., Kasama, T., et al. (2014). A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity. Angewandte Chemie International Edition, 53(33), 8645-8648. doi:10.1002/anie.201404912.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-A80F-F
Abstract
We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.