Bifunctional nanoparticle–SILP catalysts (NPs@SILP) for the selective 
deoxygenation of biomass substrates

Luska, K. L.; Julis, J.; Stavitski, E.; Zakharov, D. N.; Adams, A.; Leitner, W.

doi:10.1039/C4SC02033B

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Bifunctional nanoparticle–SILP catalysts (NPs@SILP) for the selective deoxygenation of biomass substrates

MPS-Authors

/persons/resource/persons58749

Leitner, W.
Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, 52074 Aachen, Germany ;
Research Group Leitner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

There is no public supplementary material available

引用

Luska, K. L., Julis, J., Stavitski, E., Zakharov, D. N., Adams, A., & Leitner, W. (2014). Bifunctional nanoparticle–SILP catalysts (NPs@SILP) for the selective deoxygenation of biomass substrates. Chemical Science, 5, 4895-4905. doi:10.1039/C4SC02033B.

引用: https://hdl.handle.net/11858/00-001M-0000-0024-A680-A

要旨

Ruthenium nanoparticles were immobilized onto an acidic supported ionic liquid phase (RuNPs@SILP) in the development of bifunctional catalysts for the selective deoxygenation of biomass substrates. RuNPs@SILPs possessed high catalytic activities, selectivities and recyclabilities in the hydrogenolytic deoxygenation and ring opening of C₈- and C₉-substrates derived from furfural or 5-hydroxymethylfurfural and acetone. Tailoring the acidity of the SILP through the ionic liquid loading provided a molecular parameter by which the catalytic activity and selectivity of the RuNPs@SILPs were controlled to provide a flexible catalyst system toward the formation of different classes of value-added products: cyclic ethers, primary alcohols or aliphatic ethers.