English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Nickel(I)-Komplexe mit 1,1′-Bis(phosphino)ferrocenen als Liganden

MPS-Authors
/persons/resource/persons59042

Theyssen,  Nils
Institut für Anorganische und Analytische Chemie der Universität Jena, Lessingstraße 8, D-07743 Jena, Fax: (+49) (0)3641 948102;
Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Langer, J., Fischer, R., Görls, H., Theyssen, N., & Walther, D. (2007). Nickel(I)-Komplexe mit 1,1′-Bis(phosphino)ferrocenen als Liganden. Zeitschrift für anorganische und allgemeine Chemie, 633(4), 557-562. doi:10.1002/zaac.200600350.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-52D4-B
Abstract
Nickel(I) Complexes with 1,1′-Bis(phosphino)ferrocenes as Ligands. The thermically stable monomeric Nickel(I) complexes [(dtbpf)Ni(acac)] (1) and [(dippf)NiCl] (2) were synthesized and characterized by elemental analyses, EPR spectroscopy, and by X-ray crystal structure analyses of single crystals (dtbpf: 1,1′-bis(di-tertbutylphosphino)ferrocene; dippf: 1,1′-bis(diisopropylphosphino)ferrocene). 1 is formed by reduction of Ni(acac)2 with triethylaluminium in the presence of dtbpf, together with the nickel(0) complex [(dtbpf)Ni(C2H4)]. 1 contains a NiI atom surrounded of two O- and two P donor atoms in a distorted tetrahedral coordination. 2 was obtained by reduction of [(dippf)NiCl2] with NaBH4. In 2 the nickel(I) atom adopts trigonal planar coordination.