A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations

Fürstner, Alois; Voigtländer, David; Schrader, Wolfgang; Giebel, Dirk; Reetz, Manfred T.

doi:10.1021/ol0069251

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations

MPS-Authors

/persons/resource/persons58380

Fürstner, Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Voigtländer, David
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58974

Schrader, Wolfgang
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Giebel, Dirk
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58919

Reetz, Manfred T.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Fürstner, A., Voigtländer, D., Schrader, W., Giebel, D., & Reetz, M. T. (2001). A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations. Organic Letters, 3(3), 417-420. doi:10.1021/ol0069251.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-3B01-E

Abstract

Cationic complexes of Pt(II) and other late transition metals efficiently catalyze Friedel−Crafts acylations of moderately activated arenes by carboxylic acid anhydrides. The nature of the catalytically relevant species formed from (PhCN)₂PtCl₂ and AgSbF₆ and their interactions with the substrates are studied by NMR and ESI-MS.