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Journal Article

Amine-Bis(ethene)nickel(o) Complexes; Structure of 1-Azabicyclo[2.2.2]octanebis(ethene)nickel(o)

MPS-Authors

Kaschube,  Wilfried
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pörschke,  Klaus-Richard
Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Bonrath,  Werner
Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Krüger,  Carl
Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Wilke,  Günther
Research Department Wilke, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Kaschube, W., Pörschke, K.-R., Bonrath, W., Krüger, C., & Wilke, G. (1989). Amine-Bis(ethene)nickel(o) Complexes; Structure of 1-Azabicyclo[2.2.2]octanebis(ethene)nickel(o). Angewandte Chemie International Edition, 28(6), 772-773. doi:10.1002/ange.198910110.1002/anie.198907721.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-44A1-E
Abstract
The formation of complexes from “soft” Lewis acids and “hard” bases is disfavored according to the HSAB concept. Surprisingly, however, tris(ethene)nickel(0) and amines afford crystalline complexes of the type [(amine)Ni(C2H4)2] as well as a binuclear complex, [(1,4-diazabicyclo[2.2.2]octane)Ni2(C2H4)4]. The title compound 1 is highly symmetric.