Electron spin resonance of fluorine-substituted nitro-aromatic anion radicals

Fischer, Peter H. H.; Zimmermann, Herbert

doi:10.1139/v68-638

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Electron spin resonance of fluorine-substituted nitro-aromatic anion radicals

MPS-Authors

/persons/resource/persons205323

Fischer, Peter H. H.
Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons128263

Zimmermann, Herbert
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society;
Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society;
Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://www.nrcresearchpress.com/doi/pdf/10.1139/v68-638
(Any fulltext)

https://doi.org/10.1139/v68-638
(Any fulltext)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Fischer, P. H. H., & Zimmermann, H. (1968). Electron spin resonance of fluorine-substituted nitro-aromatic anion radicals. Canadian Journal of Chemistry, 46(24), 3847-3856. doi:10.1139/v68-638.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B1D3-0

Abstract

Electron spin resonance spectra have been observed for anion radicals derived from 2-fluoro-nitro-benzene, 3-fluoro-nitrobenzene, 2,4-difluoro-nitrobenzene, 2,5-difluoro-nitrobenzene, 4-fluoro-2-nitro-phenol, 2-fluoro-6-nitrophenol, and 3-fluoro-6-nitrophenol. All radicals were generated electrolytically in dimethoxyethane/acetonitrile solution, acetonitrile, or dimethylformamide. The radicals are generally quite stable with the exception of those from 2-fluoro-6-nitrophenol and 3-fluoro-6-nitrophenol, the latter decaying with a half-life of approximately 6 min. All spectra can be interpreted completely, and coupling constants are assigned by comparison to related compounds and consistency arguments.