Stacked porphyrin-quinone triads as models for the primary charge-separation in 
photosynthesis

Pöllinger, F.; Heitele, Hans; Michel−Beyerle, Maria Elisabeth; Tercel, Moana; Staab, Heinz A.

doi:10.1016/0009-2614(93)80103-V

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Stacked porphyrin-quinone triads as models for the primary charge-separation in photosynthesis

MPS-Authors

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Tercel, Moana
Max Planck Institute for Medical Research, Max Planck Society;

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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http://www.sciencedirect.com/science/article/pii/000926149380103V/pdf?md5=1d2075232de19072342f4ad3196b9c72&pid=1-s2.0-000926149380103V-main.pdf
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https://doi.org/10.1016/0009-2614(93)80103-V
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引用

Pöllinger, F., Heitele, H., Michel−Beyerle, M. E., Tercel, M., & Staab, H. A. (1993). Stacked porphyrin-quinone triads as models for the primary charge-separation in photosynthesis. Chemical Physics Letters, 209(3), 251-257. doi:10.1016/0009-2614(93)80103-V.

引用: https://hdl.handle.net/11858/00-001M-0000-0019-AA33-C

要旨

We present time-resolved fluorescence decay measurements on a cylophane-bridged donor-acceptor triad containing a porphyrin and two different quinones in the order porphyrin—quinone1—quinone2. The time scale of photoinduced electron transfer, as well as its energetics, suggests a strong analogy with the primary charge-separation in photosynthetic reaction centers.