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Biosynthesis of anthecotuloide, an irregular sesquiterpene lactone from Anthemis cotula L. (Asteraceae) via a non-farnesyl diphosphate route

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons3778

Andersson,  S.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons3812

Boland,  W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Van Klinik, J., Becker, H., Andersson, S., & Boland, W. (2003). Biosynthesis of anthecotuloide, an irregular sesquiterpene lactone from Anthemis cotula L. (Asteraceae) via a non-farnesyl diphosphate route. Organic and Biomolecular Chemistry, 1(9), 1503-1508. doi:10.1039/b300877k.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A416-4
Abstract
Retrobiosynthetic analysis of the allergenic sesquiterpene lactone, anthecotuloide, suggested that this natural product could be formed either by head to head condensation of geranyl diphosphate with dimethylallyl diphosphate, or from farnesyl diphospha