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(6r,7r)4,5,6,7-H-2(4) -palmitoate and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine: Probes for the analysis of the stereochemical course of Delta(6)-desaturases from plants and insects

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons4213

Thum,  O.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons3927

Hertweck,  C.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons3812

Boland,  W.
Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society;

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Citation

Thum, O., Hertweck, C., Simon, H., & Boland, W. (1999). (6r,7r)4,5,6,7-H-2(4) -palmitoate and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine: Probes for the analysis of the stereochemical course of Delta(6)-desaturases from plants and insects. Synthesis, (12), 2145-2150.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A401-1
Abstract
The stereospecifically labelled (6R,7R)-[4,5,6,7-H-2(4)]-palmitic acid (14) and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine (10) have been prepared in good yield from (E)-[2,3-H-2(2)]-dodec-2-enoate 5 via biocatalytic reduction with broken cells of Clost