Synthesis and absolute configuration of the C12‐terpenoid dehydrogeosmin from 
the flower scents of Rebutia marsoneri and Dolichothele sphaerica (Cactaceae); 
a new approach to bis‐angularly substituted trans‐decalins

Huber, U.; Boland, W.; König, W. A.; Gehrcke, B.

doi:10.1002/hlca.19930760513

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Synthesis and absolute configuration of the C₁₂‐terpenoid dehydrogeosmin from the flower scents of Rebutia marsoneri and Dolichothele sphaerica (Cactaceae); a new approach to bis‐angularly substituted trans‐decalins

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Citation

Huber, U., Boland, W., König, W. A., & Gehrcke, B. (1993). Synthesis and absolute configuration of the C₁₂‐terpenoid dehydrogeosmin from the flower scents of Rebutia marsoneri and Dolichothele sphaerica (Cactaceae); a new approach to bis‐angularly substituted trans‐decalins. Helvetica Chimica Acta, 76(5), 1949-1955. doi:10.1002/hlca.19930760513.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A0F0-5

Abstract

Optically pure(+)-(4S,4aS,8aS)-1,2,3,4,4a,5,8,8a-octahydro-4,8a-dimethylnaphthalen-4a-ol ((+)-1; dehydrogeosmin) is released from flower heads of the two cactaceae Rebutia marsoneri and Dolichothele sphaerica. The absolute configuration of (+)-1 is iden