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Synthesis and absolute configuration of the c-12-terpenoid dehydrogeosmin from the flower scents of rebutia-marsoneri and dolichothele-sphaerica (cactaceae) - a new approach to bis-angularly substituted trans-decalins

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Huber, U., Boland, W., Konig, W. A., & Gehrcke, B. (1993). Synthesis and absolute configuration of the c-12-terpenoid dehydrogeosmin from the flower scents of rebutia-marsoneri and dolichothele-sphaerica (cactaceae) - a new approach to bis-angularly substituted trans-decalins. Helvetica Chimica Acta, 76(5), 1949-1955.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0012-A0F0-5
Abstract
Optically pure(+)-(4S,4aS,8aS)-1,2,3,4,4a,5,8,8a-octahydro-4,8a-dimethylnaphthalen-4a-ol ((+)-1; dehydrogeosmin) is released from flower heads of the two cactaceae Rebutia marsoneri and Dolichothele sphaerica. The absolute configuration of (+)-1 is iden