Biosynthesis of the irregular C12-terpenoid dehydrogeosmin in flower heads of 
Rebutia marsoneri Werd. (Cactaceae)

Feng, Z. F.; Huber, U.; Boland, W.

doi:10.1002/hlca.19930760714

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Biosynthesis of the irregular C₁₂-terpenoid dehydrogeosmin in flower heads of Rebutia marsoneri Werd. (Cactaceae)

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Citation

Feng, Z. F., Huber, U., & Boland, W. (1993). Biosynthesis of the irregular C₁₂-terpenoid dehydrogeosmin in flower heads of Rebutia marsoneri Werd. (Cactaceae). Helvetica Chimica Acta, 76(7), 2547-2552. doi:10.1002/hlca.19930760714.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-A001-0

Abstract

Farnesol (3a) is the precursor to the irregular C-12 terpenoid (4S,4aS,8aS)-1,2,3,4,4a,5,8,8a-octahydro-4,8a-dimethylnaphthalen-4a-ol (= dehydrogeosmin; 1). The irregular C-backbone originates from the oxidative removal of a C3 side chain from a C-15 eu