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ThPt3+xBe (x=0.08): Crystal Structure and Physical Properties

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons126632

Gumeniuk,  Roman
Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126698

Kohout,  Miroslav
Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126838

Schnelle,  Walter
Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126556

Burkhardt,  Ulrich
Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126726

Leithe-Jasper,  Andreas
Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Zitation

Gumeniuk, R., Kohout, M., Schnelle, W., Burkhardt, U., Zschornak, M., & Leithe-Jasper, A. (2017). ThPt3+xBe (x=0.08): Crystal Structure and Physical Properties. European Journal of Inorganic Chemistry, 2017(1), 179-185. doi:10.1002/ejic.201601237.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-002C-A6CD-5
Zusammenfassung
ThPt3+xBe (x = 0.08) is synthesized by arc melting of a mixture of the elements. It crystallizes with its own type of structure [space group I4/mmm (No. 139), a = 7.7370(4), c = 11.4990(6) angstrom], which can be related to the cubic Ru3Sn7 and W2Cr21C6 types. Measurements of magnetic susceptibility, electrical resistivity and specific heat indicate ThPt3+xBe (x = 0.08) to be a diamagnet [chi(0) = -9.0(3) x 10(-6) emu mol(-1)] with metallic electrical resistivity, in good agreement with the calculated electronic structure [N(E-F) = 3.2 states eV(-1) f.u.(-1)]. A chemical bonding analysis was performed by the QTAIM and ELI-D approaches.