de.mpg.escidoc.pubman.appbase.FacesBean
English
 
Help Guide Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

ThPt3+xBe (x=0.08): Crystal Structure and Physical Properties

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons126632

Gumeniuk,  Roman
Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126698

Kohout,  Miroslav
Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126838

Schnelle,  Walter
Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126556

Burkhardt,  Ulrich
Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126726

Leithe-Jasper,  Andreas
Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)
There is no public supplementary material available
Citation

Gumeniuk, R., Kohout, M., Schnelle, W., Burkhardt, U., Zschornak, M., & Leithe-Jasper, A. (2017). ThPt3+xBe (x=0.08): Crystal Structure and Physical Properties. European Journal of Inorganic Chemistry, 2017(1), 179-185. doi:10.1002/ejic.201601237.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-A6CD-5
Abstract
ThPt3+xBe (x = 0.08) is synthesized by arc melting of a mixture of the elements. It crystallizes with its own type of structure [space group I4/mmm (No. 139), a = 7.7370(4), c = 11.4990(6) angstrom], which can be related to the cubic Ru3Sn7 and W2Cr21C6 types. Measurements of magnetic susceptibility, electrical resistivity and specific heat indicate ThPt3+xBe (x = 0.08) to be a diamagnet [chi(0) = -9.0(3) x 10(-6) emu mol(-1)] with metallic electrical resistivity, in good agreement with the calculated electronic structure [N(E-F) = 3.2 states eV(-1) f.u.(-1)]. A chemical bonding analysis was performed by the QTAIM and ELI-D approaches.