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Journal Article

ThPt2: A New Representative of Close Packed Tetragonal Structures.

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons126632

Gumeniuk,  Roman
Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126838

Schnelle,  Walter
Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126556

Burkhardt,  Ulrich
Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126541

Borrmann,  Horst
Horst Borrmann, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126782

Nicklas,  Michael
Michael Nicklas, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126787

Ormeci,  Alim
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126698

Kohout,  Miroslav
Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126726

Leithe-Jasper,  Andreas
Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons126626

Grin,  Yuri
Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Gumeniuk, R., Schnelle, W., Burkhardt, U., Borrmann, H., Nicklas, M., Ormeci, A., et al. (2015). ThPt2: A New Representative of Close Packed Tetragonal Structures. Inorganic Chemistry, 54(13), 6338-6346. doi:10.1021/acs.inorgchem.5b00669.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0027-F87A-4
Abstract
ThPt2 crystallizes with unique type of structure (space group I4/mmm, a = 4.1565(1) A, c = 14.3663(7) A, Pearson symbol tI12), which belongs to the group of the close packed tetragonal structures. An analysis of the chemical bonding by the electron localizability approach reveals the formation of two-dimensional layered platinum anionic substructures interlinked by strongly polar bonds to Th. Measurements of magnetic susceptibility, electrical resistivity, and specific heat show ThPt2 to be diamagnetic with metallic type of electrical conductivity in good agreement with the calculated electronic structure (N(EF) = 0.9 states eV(-1) f.u.(-1)).