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Journal Article

Structural evolution of aragonite superstructures obtained in the presence of the siderophore deferoxamine

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons22243

Willinger,  Marc Georg
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons121734

Polleux,  J.
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons1057

Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons121206

Cölfen,  H.
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;
Universität Konstanz, Physikalische Chemie;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons121678

Nassif,  N.
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;
Laboratoire Chimie de la Matière Condensée de Paris, UMR 7574 CNRS, UPMC, Collège de France;

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c5ce00186b.pdf
(Publisher version), 6MB

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Citation

Willinger, M. G., Polleux, J., Antonietti, M., Cölfen, H., Pinna, N., & Nassif, N. (2015). Structural evolution of aragonite superstructures obtained in the presence of the siderophore deferoxamine. CrystEngComm, 17(21), 3927-3935. doi:10.1039/C5CE00186B.


Cite as: http://hdl.handle.net/11858/00-001M-0000-0027-7B57-2
Abstract
The effect of amphoteric siderophore deferoxamine on the crystallization behavior of calcium carbonate was investigated under bioinspired conditions. Amphoteric siderophore deferoxamine possesses self-organization ability, surface activity and ion-chelating properties. It induces in the present case the formation of unusual, highly organized aragonite mesocrystals during the precipitation of calcium carbonate from liquid phase. A detailed investigation of the structure and growth of the particles provides an insight into the role of the deferoxamine and its function in the crystallization process.